University of Minnesota Researchers Clear Major Hurdle in Road to High-efficiency Solar Cells
June 18, 2010 by Solar Power Engineering
Filed under Hot Solar Power Topics, Industry News, Solar Power Technologies
MINNEAPOLIS/ST. PAUL, MN — A team of University of Minnesota-led researchers has cleared a major hurdle in the drive to build solar cells with potential efficiencies up to twice as high as current levels, which rarely exceed 30 percent.

By showing how energy that is now being lost from semiconductors in solar cells can be captured and transferred to electric circuits, the team has opened a new avenue for solar cell researchers seeking to build cheaper, more efficient solar energy devices. The work is published in this week’s Science.
A system built on the research could also slash the cost of manufacturing solar cells by removing the need to process them at very high temperatures.
The achievement crowns six years of work begun at the university Institute of Technology (College of Science and Engineering) chemical engineering and materials science professors Eray Aydil and David Norris and chemistry professor Xiaoyang Zhu (now at the university of Texas-Austin) and spearheaded by U of M graduate student William Tisdale.
In most solar cells now in use, rays from the sun strike the uppermost layer of the cells, which is made of a crystalline semiconductor substance—usually silicon. The problem is that many electrons in the silicon absorb excess amounts of solar energy and radiate that energy away as heat before it can be harnessed.
An early step in harnessing that energy is to transfer these “hot” electrons out of the semiconductor and into a wire, or electric circuit, before they can cool off. But efforts to extract hot electrons from traditional silicon semiconductors have not succeeded.
However, when semiconductors are constructed in small pieces only a few nanometers wide — “quantum dots” — their properties change.
“Theory says that quantum dots should slow the loss of energy as heat,” said Tisdale. “And a 2008 paper from the University of Chicago showed this to be true. The big question for us was whether we could also speed up the extraction and transfer of hot electrons enough to grab them before they cooled. ”
In the current work, Tisdale and his colleagues demonstrated that quantum dots—made not of silicon but of another semiconductor called lead selenide — could indeed be made to surrender their “hot” electrons before they cooled. The electrons were pulled away by titanium dioxide, another common inexpensive and abundant semiconductor material that behaves like a wire.
“This is a very promising result,” said Tisdale. “We’ve shown that you can pull hot electrons out very quickly – before they lose their energy. This is exciting fundamental science.”
The work shows that the potential for building solar cells with efficiencies approaching 66 percent exists, according to Aydil.
“This work is a necessary but not sufficient step for building very high-efficiency solar cells,” he said. “It provides a motivation for researchers to work on quantum dots and solar cells based on quantum dots.”
The next step is to construct solar cells with quantum dots and study them. But one big problem still remains: “Hot” electrons also lose their energy in titanium dioxide. New solar cell designs will be needed to eliminate this loss, the researchers said.
Still, “I’m comfortable saying that electricity from solar cells is going to be a large fraction of our energy supply in the future,” Aydil noted.
The research was funded primarily by the U.S. Department of Energy and partially by the National Science Foundation. Other authors of the paper were Brooke Timp from the University of Minnesota and Kenrick Williams from UT-Austin.
University of Minnesota
www1.umn.edu/twincities/index.php
Solar Alternatives for Energy Generation
May 5, 2010 by Solar Power Engineering
Filed under Featured Solar Power Articles, Photovoltaic, Solar Power Technologies
By John R. Gyorki, Editorial Director
Theoretical scientists have discovered many techniques for converting sunlight into electric energy, but only photovoltaic (PV) and concentrating solar power (CSP) systems show the most promise for practical applications.
It’s always fun and interesting for engineers to focus on the technical development of emerging technologies such as solar energy and specifically, photovoltaics. But we often tend to forget the influence of politics and the economy. Sometimes their influence outweighs the technical challenges, and most assuredly in a negative way — at first. But in the end, in an imperfect world, we have to face and be satisfied with compromises. The intention of politics is to help secure funding and establish safe rules and regulations for design, development, installation, and maintenance.
Solar Power Equipment Payback Time
China, Germany, Japan, Taiwan, and the USA are today’s leaders in solar cell manu-facturing, but many other countries are actively pursuing this technology. It has been noted that solar power equipment manufacturing and installation rapidly accelerates in countries with significant government R&D funding, and strong tariff, tax credits, and other incentive-type legislation.
One major objective of each of these countries is to lower the cost of electric energy. Solar power equipment manufacturers, universities, and government agencies can do this by working to improve PV and CSP efficiency, increase power ratings, and reduce the cost of manufacturing. And, the main goal of ongoing PV research everywhere is to increase solar-cell efficiency.
Of course, the ultimate goal is to lower the total cost of producing solar electric power to make it more attractive to the consumer than fossil electric power. This total cost depends on the cost of solar power equipment materials and manufacturing, cost of installation and maintenance, and finally the amount of produced electric power directly linked to solar cell efficiency.
Now, how can we calculate the total cost? We use what is called, “Energy Payback Time” (EPBT), but, unfortunately, this term is often misunderstood. For solar power equipment, EPBT means the length of time the system operates and produces electric energy equal to the total amount of energy required to produce all of its own system components. The U.S. Department of Energy estimates that the EPBT for a typical solar module made of single-crystal silicon cells is 2.7 years. Obviously, this number must drop considerably, and soon.
The Nitty-Gritty of Photovoltaics
The first type of conversion process, photovoltaic energy systems, transforms sunlight into electrical energy using photovoltaic cells or solar cells by way of its inherent photoelectric effect.
For many years, PV power devices were applied to small consumer products such as battery chargers, calculators, road signs, sidewalk markers, remote homes and farms, and a few large solar power stations. They also served as the main power source for space satellites, craft, and stations.
Solar cell theory is relatively simple. When a solar cell is exposed to sunlight, some photons reflect off the solar cell surface and some low-energy photons pass through the cell without affecting it. But the solar cell’s silicon semiconductor layer absorbs the remaining photons with an energy greater than the silicon band-gap value. These photons knock negatively charged electrons out of their orbits and generate a flow of free electrons and complementary, positively charged holes.
Solar cells are structured to force all free electrons to move in the same direction, which produces direct electric current. Several techniques may be used, but in the most mature and widely used type, each solar cell is fabricated as a large silicon p-n junction. This arrangement is similar to a diode; the current can flow only in one direction. It is widely known as “drift charge carrier separation.”
The diagram shows the construction of a crystalline silicon (c-Si) photovoltaic cell, which should help to better understand the PV technology. Crystalline silicon is the most widely used material for PV cells. An n-type dopant diffuses into a p-type silicon wafer and creates the p-n junction. Depending on the way it is made, it might start out with an n-type waver, followed by a p-type layer.
Then, front and back metal contacts are formed on either side of the wafer so the cell can be electrically connected to an external circuit. Electrical conductors or wires connect to each contact, and when the conductors are connected to the load, the circuit is complete.
The n-type and p-type layers sit side-by-side on the silicon wafer. Some excess electrons from the n-type layer move into the p-type layer so holes remain in their place; holes move from the p-layer into the n-layer. The electrons and holes create an electric field in the junction area of the semiconductor.
During PV cell operation, this field forces the electrons (that are freed by the photons in the p-type layer) to move to the top of the n-type layer while the holes move to the p-type layer. The electrons flow through the contact, wiring, and load in the outside circuit and then return to the p-type layer where they recombine with the holes. Of course, the notation for the conventional direction of current flow is opposite to the direction of electron flow.
Not every photon frees an electron, and not all the potential electric power is necessarily collected. The term, “solar cell energy conversion efficiency,” defines the percentage of power converted from absorbed sunlight to electric power, which is delivered to the load. That is:
η = Pm /E Ac
Where:
η = energy conversion efficiency, %
Pm = maximum power point, W
E = input light irradiance, W/m²
Ac = solar cell surface area, m²
Input light irradiance, E, is the amount of solar light power divided by surface area of the PV cell. The maximum electric power, Pm, is generated by the cell at the point of maximum irradiance, which for sun-tracking systems occurs at what is called “solar noon.” In PV lingo, this solar noon is not necessarily 12:00 PM, but the mid-time between sunrise and sunset.
The U.S. Department of Energy estimates that the efficiency of commercial PV power systems available today is in a range of 7% to 17%. The main reason for these seemingly low numbers is that photons comprising only a small part of the solar spectrum (0.3 to 0.6 µm, which have energy greater than the solar cell band gap) can produce free electrons.
Four types of materials are commonly used for fabricating modern photovoltaic cells and arrays: mono-crystalline silicon, polycrystalline silicon, amorphous silicon, and gallium arsenide. Mono-crystalline silicon is one of the most common PV cell materials, however its potentially high efficiency is still limited due to the quite small number of photons it can absorb, and as a result, the cost-per-watt is relatively high. Polycrystalline silicon cells and amorphous silicon cells have lower efficiency. Gallium Arsenide types offer much higher efficiency, but their production cost is relatively high and currently limits its use to special applications, such as aerospace.
Thin film is the preferred choice for fabricating cells. Thin film technology offers one of the lowest production costs when the thin-film cell base is made of steel, glass, or a polymer instead of silicon. The active cell material is built from 1 to 10 µm thick by depositing several layers of extremely thin film. However, this design also has somewhat lower efficiency, meaning that a larger size PV cell is needed to generate the same amount of electric power as a smaller size, high-efficiency cell.
These devices typically use several polycrystalline and single-crystalline films. Polycrystalline thin films are made of silicon, cadmium telluride (CdTe), copper indium diselenide (CIS), or copper indium gallium diselenide (CIGS). These materials have high absorptivity, which helps increase the conversion efficiency. Single-crystalline thin films are made of gallium arsenide (GaAs) or several other materials.
Efficiency can be also increased by fabricating PV cells from two or more different cells, one on top of another. The cells in the stack have junctions of different band gaps. This construction is called a multi-junction solar cell. For instance, in a three-cell multi-junction design, the top cell has the highest band gap and absorbs the photons with higher energy level. The cell below it has a lower band gap and absorbs photons that pass through the top cell. The third cell has even lower band gap energy and absorbs the photons that pass through the two cells above it. Thus, more photons are absorbed compared to a single cell arrangement, and the efficiency is much greater — by about 35%.
The size of a single PV cell ranges from about 1 to 10 cm across, and other than in small calculators, using just a single cell is not practical because the voltage and current out of one cell are too low for most other applications. Depending on the technology, a typical PV cell voltage is approximately 0.5V with a maximum power of 2 W.
Most applications require several cells interconnected into a PV module, frequently called a PV panel. Mechanically, a frame supports all cells in a module. Usually, modules generate a particular voltage with current proportional to the amount of light falling onto the module. The most common solar module output voltage is 12V. To increase the voltage, current, or both, the modules are connected in series and/or parallel. These assemblies are called solar arrays.
PV Power systems
Two types of solar power systems are widely used: off-grid or stand-alone and grid-connected. The light-to-electric energy conversion factor is about the same, but the electric energy storage and distribution are accomplished differently.
In a typical off-grid or stand-alone solar power generating system the PV array connects to a charge/discharge controller that directs and controls solar-generated dc electric current to charge the storage battery. Lead-acid batteries are commonly used for energy storage, and depending on how many batteries are connected in series, the nominal battery voltage is 12, 24, or 48 V.
Typical controllers include temperature compensation, provide complete isolation between the control and power circuits, and have light-detection driven on/off switching and programmable timers. The battery side includes overcharging and reverse-polarity protection, low battery voltage cut-off, and fault warning. On the load side, controllers typically include output overload, over-voltage, reverse-polarity, and short-circuit protection. The solar array is protected against reverse polarity and reverse current flow at night.
The controller also regulates the battery discharge into the load. The battery load of a stand-alone system is a dc-to-ac inverter, which converts 12, 24, or 48Vdc current into 110Vac, 60Hz or 220Vac, 50Hz alternating current. Inverters with operating efficiency of 90%, tight output voltage tolerances, and low harmonic distortion are common. They typically come with input reverse polarity, over-voltage, and under-voltage protection. The output has overload, short-circuit, and thermal shutdown protection.
A typical grid-connected solar power system includes a solar array and a grid-connected inverter. It does not need a storage battery; it converts the dc current generated by the solar array directly into high voltage alternating current that is fed into the electric utility grid. Depending on the country and standard power utility grid arrangement, the inverter output frequency is 50 or 60Hz, and the voltage is in a range between 180 and 440Vac.
Similar to any power line equipment solar power equipment manufacturers typically obtain certification from one of the testing service providers. Underwriters Laboratories Inc. (UL), Institute of Electrical and Electronics Engineers (IEEE), and International Electrotechnical Commission (IEC) are the three main agencies offering solar power equipment certification. They are considered authorities in this field and their certificates are widely recognized.
Concentrating Solar Power Technology
Concentrating Solar Power (CSP) systems are intended for large-scale electric power generation, and only several installations exist today. Compared to PV devices, the light-to-electricity conversion process used in these systems is more complex.
CSP systems use large parabolic mirrors or lenses to concentrate solar light on a receiver, which is filled with working or heat-transfer fluid, such as oil, suspended at the focal point. Concentrated sunlight heats the oil and forces it to flow into a heat exchanger or solar steam generator. It then heats another fluid (water) and converts it to steam. The steam drives a turbine generator that produces electricity and at the same time drives the pumps. After leaving the turbine, the steam cools in the condenser and returns to water, which is fed again into the heat exchanger—and the cycle repeats.
Only three types of CSP systems have proved practical so far: parabolic dish, solar trough, and solar power tower. In the first system, a round parabolic dish reflector positions the receiver at its focal point. The dish turns in two axes to track the sun from morning until evening, which provides the highest efficiency among the three systems.
The trough system is very similar in operation, but instead of the dish reflector, it uses a series of long, linear parabolic reflectors. The receiver tube is suspended along the focal line of the trough. The troughs also follow the sun, but can turn only about one axis. So, its sun-tracking efficiency is not as good as the dish design. Nevertheless, trough systems are the most cost effective of the three and have the largest number of installations.
The receiver of the solar power tower is positioned at the top of the central tower surrounded by an array of reflectors, also called heliostats, installed at ground level. Each reflector tracks the sun during the day and keeps the beam of concentrated light on the receiver. Tower systems have high efficiency and superior energy storage capabilities.
For more information, go to:
SUNTECH:
http://www.suntech-power.com
Watlow:
http://www.watlow.com
DOE:
http://www.eere.energy.gov
XsunX:
http://www.xsunx.com








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